(4-Chlorobenzohydrazidato-κ2 N′,O)[2-(4-chlorobenzoylhydrazono-κ2 N,O)propionato(2−)-κO]oxidovanadium(V)
نویسندگان
چکیده
In the crystal structure of the title compound, [VO(C(7)H(6)ClN(2)O)(C(10)H(7)ClN(2)O(3))], the V(V) atom is N,O-chelated by the chloro-benzoyl-hydrazidate anion and O,N,O'-chelated by the (chloro-benzoyl-hydrazono)propionate dianion. The distorted octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds into a linear chain parallel to [010].
منابع مشابه
(4-Chlorobenzohydrazidato-κ2 N′,O)[2-(4-chlorobenzoylhydrazinylidene-κ2 N 1,O)-3-phenylpropionato(2−)-κO 1]oxidovanadium(V) methanol monosolvate
The V(V) atom in the title compound, [V(C(7)H(6)ClN(2)O)(C(16)H(11)ClN(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoyl-hydrazidate anion and O,N,O'-chelated by the (benzoyl-hydrazinyl-idene)propionate dianion. The distorted octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. The mononuclear and solvent mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds ab...
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In the title complex, [V(C(15)H(12)N(2)O(4))(C(2)H(5)O)O], the V(V) ion is coordinated by an oxide O atom, an ethano-late anion and two O atoms and one N atom from the tridentate benzo-hydrazidate dianion in a distorted square-pyramidal geometry; the V atom is displaced by 0.4748 (8) Å from the basal plane towards the axial oxide O atom. An intra-molecular O-H⋯N hydrogen bond occurs in the benz...
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The title oxidovanadium(V) complex, [V(C(17)H(16)N(2)O(3))(CH(3)O)O], was obtained by the reaction of 3-eth-oxy-2-hy-droxy-benzaldehyde, 4-methyl-benzohydrazide and vanadyl sulfate in methanol. The V(V) atom is coordinated by the O,N,O'-tridentate Schiff base ligand, one methano-late O atom and one oxide O atom, forming a distorted VO(4)N square-pyramidal coordination geometry. The oxide O atom...
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